EC-Safety Data Sheet (acc. 1907/2006/EC) revised: 26.05.2015

 
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Titanium-Nitride-Coating Grade E
Use of the substance/preparation:
High temperature lubrication and release agent.
 
 
 
1.2 Company/undertaking identification:
Büro für angewandte Mineralogie · Dr. Stephan Rudolph
Hinkes Weißhof 50 · D-47918 Tönisvorst
Telefone no. +49(0)2156 80072
Fax no.+49(0)2156 80835
Email: dr.rudolph@a-m.de

 

1.3 Emergency telephone number:
+49(0)2156 80072 (Mo-Fr 8:00-15:00h)
 
 
2. Hazards Information
2Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R11: Highly flammable.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
Classification system:
The classification is in line with current EC lists. It is extended, by information from technical literature and company information.
 
2.2 Label elements
Produktbezeichnung Boron-Nitride-Coating Grade E
Piktogramme: GHS02
 
imageghs07
 
Signal word Danger
·Hazard statements
H225 Highly flammable liquid and vapour.
·Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection. P240 Ground/bond container and receiving equipment.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
 
3 Composition/information on ingredients
3.1 Chemical characterization (substance):

No.

Substance

CAS REG No.

EINECS No.

Sym-bol

Risk State-ment

1

Titanium nitride

25583-20-4

247-117-5

2

Ethanol

64-17-5

200-578-6

F

11

 

4. First-aid measures
4.1 General information:
4.2 Inhalation: Remove person to fresh air. Seek medical attention if feeling unwell.
4.3 Eye contact: Rinse out with plenty of water for at least 15 minutes and seek medical attention.
4.4 Skin contact: Wash off with plenty of water and soap. Remove contaminated clothing.
4.5 Ingestion: Drink plenty of water. Summon doctor if necessary.

 

5. Fire-fighting measures
5.1 General information: Product is highly flammable. Keep away from sources of ignition. Vapour is heavier than air and forms explosible mixtures with air. Take means to prevent electrostatic charging.
5.2 Suitable extinguishing media: CO2, foam, powder.
5.3 Extinguishing media which must not be used for safety reasons: Not applicable.
5.4 Special exposure hazards arising from the substance or preparation itself, combustion products or resulting gases: Not applicable.
5.5 Special protective equipment for fire-fighters: As in any fire, wear self-contained, pressure-demand breathing apparatus and full protective gear.

 

6. Accidental release measures
6.1 Personal protection: Observe protection measures from other sections.
6.2 Environmental protection: Keep away from drainage, waters and soil.
6.3 Methods for cleaning up: Take up with liquid-absorbent material and store in a closed container.
6.4. Additional information: Remove sources of ignition.

 

7. Handling and storage
7.1 General information: No special means required.
7.2 Handling: Use only in well-ventilated working places.
7.3 Storage: Keep container tightly closed. Store in a well-ventilated and cool place.

 

8. Exposure controls/personal protection
8.1 Additional information for system design: Use appropriate local exhaust ventilation to control airborne levels which may be generated by spraying this product.
8.2 Components with specific control parameters:
MAK Germany (max. workplace conc.) Ethanol: 1000ppm or 1900mg/m³.
8.3 Personal protection:
General protection and hygiene measures: Avoid contact with skin and eyes. Do not inhale vapours. Take off immediately contaminated clothing. Observe usual precaution measures when handling chemicals.
Respiratory Protection: Required above control parameters.
Eye Protection: Side-shielded safety goggles.
Hand Protection: Protective gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· For the permanent contact gloves made of the following materials are suitable: Recommended thickness of the material: 0.7 mm
Fluorocarbon rubber (Viton)
Value for the permeation: Level ≥ 480 min
· As protection from splashes gloves made of the following materials are suitable: Recommended thickness of the material: 0.6 mm
Natural rubber, NR
Value for the permeation: Level ≥ >120
Skin protection: Not required.

 

9. Physical and chemical properties

Appearance:

liquid,

Colour:

brown

Odour:

characteristic

Boiling point / boiling range:

78°C

Melting point / melting range:

-117°C

Flash point:

12°C

Flammability (solid/gas:)

425°C

Explosive properties:

3,5-15 Vol.-%

Oxidizing properties:

N/A

Vapour pressure:

59hPa at 20°C

Relative Density (water = 1)

0.95

Solubility

Water soluble:

dilutable

Fat solubility

Partition coefficient n-octanol/water

pH:

N/A

Other data:

 

10. Stability and reactivity
10.1 General information: There are no known hazardous reactions when stored and used appropriately.
10.2 Conditions to avoid: None known.
10.3 Materials to avoid: Strong oxidizing agents, alkali metals, chromium trioxide, calcium hypochlorite, potassium perchlorate, manganese perchlorate, perchloric acid, permangante acid, mercury nitrate, silver nitrate, silver perchlorate, nitrogen dioxide, hydrogen peroxide.
10.4 Hazardous decomposition products: There are no known hazardous decomposition products for this material.
10.5 Hazardous polymerisation: Product will not undergo polymerisation.

 

11. Toxicological information
11.1 General information:According to our present state of knowledge there are no known damages to expect when used appropriately.
11.2 Acute toxicity: LD50-(oral, rat): 7060mg/kg (literature data for ethanol), LC50 (inhal., rat) 38mg/l/10.0h (literature data for ethanol)
11.3 Additional information: Acc. to literature ethanol causes mucosal irritation, slight irritation to skin, degreasing skin, narcotic effects, liver damage possible.

 

12. Ecological information
Product is well biodegradable. No ecological problems will be expected from appropriate usage.Dump into sewage treatment plants only diluted and in very small quantities.

 

13. Disposal considerations
May be disposed of in a landfill according to local, state and federal regulations after chemical-physical pre-treatment, if need consider contamination by usage.
EWC-Codes:
16 05 02 (Product) inorganic chemical waste,
15 01 02 (Package) plastic package,
15 01 01 (Outer package) paper and cardboard package.

 

14. Transport information
GGVS/GGVE: Class 3/3b (Germany)
ADNR: Class 3/3b
Name: contains ethanol
Symbol: flammable liquid
Express : 6000ml/parcel
Post: 250ml/container, max. 500ml/parcel.

 

15. Regulatory information
15.1 General information:The usual precaution measures should be observed when handling chemicals. This product is determined for industrial use and comparable applications (e.g. research and development) only. It is not intended for food, drug or household use.
15.2 Labelling according to ec-directives:
Indication of danger of the product: F = Highly flammable
Risk statement EC/R: R11 Highly flammable.
Safety statement EC/S: S7 Keep container tightly closed.
S16 Keep away from sources of ignition - No smoking.
15.3 National regulations:
German water pollution class: 1, i. e. low water polluting product.
VBF german regulation on combustible liquids: B

 

16. Other information
N/A = not applicable, N/D = not determined

 

This EC safety data sheet serves only as a description of this product with regard to safety requirements and means no guarantee of properties of the described product. We believe that such information is accurate and reliable as of the date of this safety data sheet; but no representation, guarantee or warranty, expressed or implied, is made. We urge persons receiving this information to make their own determination as to the information's suitability and completeness for their particular application. We further urge purchasers to determine suitability of this product for their application prior to use by making their own tests, also with regard to possible applicational influences. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way with the handling, storage, use or disposal of the product.


© 2015 Büro für angewandte Mineralogie · Dr. Stephan Rudolph · D-47918 Tönisvorst


These recommendations are believed to be correct. However, no guarantee of their accuracy is given. Therefore, purchasers shall make their own tests to determine suitability for their use. These products are offered for industrial and related uses (e.g. research and development) only. However the user must take the necessary precautions appropriate for products containing chemicals. This description does not imply the absence of any patents, the responsibility whatsoever solely rests with the user.