EC-Safety Data Sheet (acc 1907/2006/EC) revised 26.05.2015
 
 
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Graphite Aerosol GS
Use of the substance/preparation:
High temperature lubrication and release agent
 
1.2 Company/undertaking identification:
Büro für angewandte Mineralogie · Dr. Stephan Rudolph
Hinkes Weißhof 50 · D-47918 Tönisvorst
Telefone no. +49(0)2156 80072
Fax no.+49(0)2156 80835
Email: dr.rudolph@a-m.de

 

1.3 Emergency telephone number:
+49(0)2156 80072 (Mo-Fr 8:00-15:00h)

 

2. Hazards information
2.1 Classification of the substance or mixture
Regulation (EC) No 1272/2008
H222 - Extremely flammable aerosol
Classification and labeling has been done according to 67/548/EEC with amendments and 1999/45/EC with amendments. This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
FLAMMABLE AEROSOLS Category 1
Symbols/Pictograms F+ - Extremely flammable
R-Phrases R12 - Extremely flammable
2.2 Label element
Product name ALU-STOP BN-A Boron Nitride Aerosol
Pictograms: GHS02

imageghs02

signal word DANGER
Hazard Statements
H222 - Extremely flammable aerosol
H229 - Pressurized container: May burst if heated
precautionary statements
H222 - Extremely flammable aerosol
H229 - Pressurized container: May burst if heated
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P211 - Do not spray on an open flame or other ignition source
P251 - Do not pierce or burn, even after use
P281 - Use personal protective equipment as required
P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
P202 - Do not handle until all safety precautions have been read and understood
P273 - Avoid release to the environment
P304 + P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing

 

3 Composition/information on ingredients
3.1 Chemical characterization (substance):

No.

Substance

CAS REG No.

EINECS No.

Sym-bol

Risk State-ment

1

Graphite

7782-42-5

231-955-3

2

2-Propanol

67-63-0

200-661-7

F

11

3

Propane

74-98-6

200-827-9

F+

12

4

Butane

106-97-8

200-450-8

F+

12

 

3. Hazards information
3.1 Critical hazards to man and environment: Extremely flammable. The solvent vapour is heavier than air and can accumulate near the floor and in hollows. Danger of bursting of container by overheating.

 

4. First-aid measures
4.1 General information: -
4.2 Inhalation: Remove person to fresh air, if necessary seek medical attention. In case of unconsciousness put person into recovery position and give oxygen or start artificial respiration.
4.3 Eye contact: Flush with lot of water for some time while holdng the eye wide open. If necessary, seek medical attention.
4.4 Skin contact: Wash contaminated areas thoroughly with soap and water. Seek medical attention if irritation persists.
4.5 Ingestion: Give fluids in large quantity and seek prompt medical attention. Never give anything by mouth to an unconscious person.

 

5. Fire-fighting measures
5.1 General information: -
5.2 Suitable extinguishing media: CO2, fire-ex powder or water spraying jet. Larger fires should be fight with water spraying jet or alcohol-steady foam.
5.3 Extinguishing media which must not be used for safety reasons: Water in the full jet.
5.4 Special exposure hazards arising from the substance or preparation itself, combustion products or resulting gases: Overheated pressurized packages may burst, and may hurl away with large force (danger of injury, danger of explosive vapour).
5.5 Special protective equipment for fire-fighters: As in any fire, wear self-contained, pressure-demand breathing apparatus and full protective gear.

 

6. Accidental release measures
6.1 Personal protection: Ventilate sufficiently, keep away of sources of ignition, use protective gloves, sort out leaky containers.
6.2 Environmental protection: Prevent entering in drains, soil or water.
6.3 Methods for cleaning up: Remove spilled product with absorbent material, sort out leaking cans and remove as described under "disposal consideration".

 

7. Handling and storage
7.1 General information: Container is under pressure. Protect against exposure to the sun and temperatures exceeding 50°C. Do not burn or try to open violently, even when empty. Do not spray onto flames or smouldering objects. Without sufficient ventilation the formation of explosives vapours is possible. Must not get into the hands of children. Do not inhale aerosol. Do not place or store containers in the range of sparks, ignition sources or sources of heat.
7.2 Handling: Use only in well ventilated areas. Keep away from sources of ignition - Do not smoke.
7.3 Storage: Do not expose to the sun. Do not store in the car interior. Observe the storage instructions of the TRG300 for inflammable aerosols.

 

8. Exposure controls/personal protection
8.1 Additional information for system design: Observe occupational exposure limits:
8.2 Components with specific control parameters:
MAK (TWA-8 hours): propane/butane 1000ppm
MAK (TWA-8 hours): 2-propanol 500ppm
8.3 Personal protection:
General protection and hygiene measures: Avoid contact with skin and eyes. Take off immediately contaminated clothing. After work and before breaks wash hands thoroughly with water and soup. Do not eat, drink or smoke during work. Observe usual precaution measures when handling chemicals.
Respiratory Protection: In case of insufficient ventilation of working area.
Eye Protection: Side-shielded safety goggles.
Hand Protection: Protective gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· For the permanent contact gloves made of the following materials are suitable: Recommended thickness of the material: 0.7 mm
Fluorocarbon rubber (Viton)
Value for the permeation: Level ≥ 480 min.
· As protection from splashes gloves made of the following materials are suitable: Recommended thickness of the material: 0.6 mm
Natural rubber, NR
Value for the permeation: Level ≥ 120min.
Skin protection: Not required.

 

9. Physical and chemical properties

Appearance:

Aerosol

Colour

black

Odour:

characteristic

Boiling point / boiling range:

N/A

Melting point / melting range:

N/A

Flash point:

N/A

Flammability (solid/gas:)

>300°C

Explosive properties:

N/A

Oxidizing properties:

during overheating

Vapour pressure:

3,8 bar (20°C); 7,8 bar (50°C)

Relative density (water = 1)

<1

Solubility

Water soluble:

partly soluble

Fat solubility

Partition coefficient n-octanol/water

pH:

N/A

Other data:

 

10. Stability and reactivity
10.1 General information: There are no known hazardous reactions when stored and used appropriately.
10.2 Conditions to avoid: Danger of bursting at temperatures exceeding 50°C.
10.3 Materials to avoid: None known.
10.4 Hazardous decomposition products: There are no known hazardous decomposition products for this material.
10.5 Hazardous polymerization: Product will not undergo polymerization.

 

11. Toxicological information
11.1 General information: Contains propane/butane and ethanol. There are no known toxicological characteristics of this product.
11.2 Acute toxicity: LD50 (oral, rat): 4570mg/kg (literature data for 2-propanol). Inhalation of large amount of propellant gas and solvent vapour can cause narcotic effects. Solvent degreases skin with intensive contact. Permanent repetition can cause dermatitic effects.

 

12. Ecological information
No applicable data available. No ecological problems will be expected from appropriate usage. The components in this formulation do not meet the criteria for classification as PBT or vPvB.

 

13. Disposal considerations
Empty containers completely (incl. propellant gas). Then no more special measures for the empty can.
EWC-Codes:
15 01 04 (Package, empty) package metallic,
16 05 01 (Package, not empty) industrial aerosol containers,
16 05 01 (Package, not empty) aerosols, separately collected, industrial and household,
15 01 01 (Outer package) paper and cardboard package.

 

14. Transport information

Classification

Not applicable.

GGVS/ADR:
1950
pressurized container, limited quantity
Klasse: 2
Ziffer: 5F
GGVE/RID:
pressurized container, limited quantity
Klasse: 2
Ziffer: 5F
GGVSee/IMDG:
Aerosol, limited quantity *)
Class: 2 UN-No: 1950
Pkg-Group: II
EmS-No: 2-13 MFAG-No: 310
GGVSee/IMDG:
Aerosol, flammable n.o.s. containing propane/butane
Class: 2,1 UN-No: 1950
Sub-Risk: -(Pkg-Group II)
Pkg-Notes: Pass. 203/75kg
Cargo 203/150kg
 
 
The packing group is applicable only for the outside packaging and does not have to be mentioned in the "shippers declaration".
*) >45% flammable constituents GGVSee/IMDG-classification acc. the 28th amendment

 

15. Regulatory information
15.1 General information: The usual precaution measures should be observed when handling chemicals. This product is determined for industrial use and comparable applications (e.g. research and development) only. It is not intended for food, drug or household use.
15.2 Labeling according to ec-directives: Warning notes and classification as "highly flammable" in accordance with the aerosol guideline TRG300. Container is under pressure. Protect from sunlight and temperatures exceeding 50°C. Do not open or burn even after usage. Do not spray into open flames or smouldering objects. Do not breath in spray dust. Avoid skin and eye contact. During usage the formation of explosive/highly flammable vapour is possible. Keep away from sources of ignition - Do not smoke. Use only in well ventilated areas. Keep out of reach of children.
Indication of danger of the product: -
Risk statement EC/R: -
Safety statement EC/S: -
15.3 National regulations:
Indication: Aerosol container regulation TRG300 (special request for pressurized packages)
Water contamination class: 1, i. e. low water polluting product.

 

16. Other information
N/A = not applicable, N/D = not determined

 

Proofed over pressure of the cans: 12bar
Does not contain chlorinated fluorohydrocarbons or chlorinated hydrocarbons.

 

This EC safety data sheet serves only as a description of this product with regard to safety requirements and means no guarantee of properties of the described product. We believe that such information is accurate and reliable as of the date of this safety data sheet; but no representation, guarantee or warranty, expressed or implied, is made. We urge persons receiving this information to make their own determination as to the information's suitability and completeness for their particular application. We further urge purchasers to determine suitability of this product for their application prior to use by making their own tests, also with regard to possible applicational influences. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way with the handling, storage, use or disposal of the product.


© 2015 Büro für angewandte Mineralogie · Dr. Stephan Rudolph · D-47918 Tönisvorst


These recommendations are believed to be correct. However, no guarantee of their accuracy is given. Therefore, purchasers shall make their own tests to determine suitability for their use. These products are offered for industrial and related uses (e.g. research and development) only. However the user must take the necessary precautions appropriate for products containing chemicals. This description does not imply the absence of any patents, the responsibility whatsoever solely rests with the user.